The Resource Optical metamaterials by block copolymer self-assembly, Stefano Salvatore

Optical metamaterials by block copolymer self-assembly, Stefano Salvatore

Label
Optical metamaterials by block copolymer self-assembly
Title
Optical metamaterials by block copolymer self-assembly
Statement of responsibility
Stefano Salvatore
Creator
Author
Subject
Genre
Language
eng
Summary
Metamaterials are artificially designed materials engineered to acquire their properties by their specific structure rather than their composition. They are considered a major scientific breakthrough and have attracted enormous attention over the past decade. The major challenge in obtaining an optical metamaterial active at visible frequencies is the fabrication of complex continuous metallic structures with nanometric features. This thesis presents the fabrication and characterization of optical metamaterials made by block copolymer self-assembly.℗l This℗l approach allows fabrication of an intriguing and complex continuous 3D architecture called a gyroid, which is replicated into active plasmonic materials such as gold. The optical properties endowed by this particular gyroid geometry include reduction of plasma frequency, extraordinarily enhanced optical transmission, and a predicted negative refractive index. To date, this is the 3D optical metamaterial with the smallest features ever made
Member of
Cataloging source
GW5XE
http://library.link/vocab/creatorName
Salvatore, Stefano
Dewey number
620.11
Illustrations
illustrations
Index
no index present
LC call number
TK7871.15.M48
Literary form
non fiction
Nature of contents
  • dictionaries
  • bibliography
Series statement
Springer theses,
http://library.link/vocab/subjectName
  • Metamaterials
  • Optical materials
  • Polymers
  • Self-assembly (Chemistry)
  • TECHNOLOGY & ENGINEERING
  • TECHNOLOGY & ENGINEERING
  • Metamaterials
  • Optical materials
  • Polymers
  • Self-assembly (Chemistry)
  • Electronic devices & materials
  • Polymer chemistry
  • Nanotechnology
  • Materials science
Label
Optical metamaterials by block copolymer self-assembly, Stefano Salvatore
Link
https://ezproxy.lib.ou.edu/login?url=http://link.springer.com/10.1007/978-3-319-05332-5
Instantiates
Publication
Copyright
Note
"Doctoral thesis accepted by the University of Cambridge, UK."
Antecedent source
unknown
Bibliography note
Includes bibliographical references
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
  • Supervisor's Foreword; Abstract; Contents; 1 Introduction; 2 Background; 2.1 Block Copolymers; 2.1.1 Triblock Copolymer Morphologies; 2.1.2 Gyroid Morphology; 2.1.3 Block Copolymer Applications; 2.2 Metamaterials; 2.2.1 Chiral Metamaterial; 2.2.2 Surface Plasmons; 2.2.3 Gyroid Theoretical Models; References; 3 Gyroid Metamaterial Fabrication; 3.1 Introduction; 3.2 Substrate Preparation; 3.3 I-S-O Triblock Copolymer; 3.3.1 Thermal Annealing; 3.3.2 Drying-Annealing; 3.3.3 Solvent Vapour Annealing; 3.4 PFS-b-PLA Diblock Copolymer; 3.5 Metal Deposition; 3.6 Film Morphology Control
  • 3.7 ConclusionsReferences; 4 Gyroid Metamaterial Characterization; 4.1 Introduction; 4.2 Transmission Electron Microscopy; 4.3 Electric Characterization; 4.4 Optical Properties; 4.4.1 Single Gyroid; 4.4.2 Film Thickness Effects; 4.4.3 Disorder Effects; 4.4.4 Double and Silver Gyroids; 4.5 Conclusions; References; 5 Tuning Methods; 5.1 Introduction; 5.2 Unit Cell Control; 5.3 Filling Fraction Variation; 5.4 Surrounding Medium Effects; 5.5 Conclusions; References; 6 Hollow Gyroid; 6.1 Introduction; 6.2 Hollow Gyroid Fabrication; 6.2.1 Optical Properties; 6.3 Carbon Hollow Gyroid
  • 6.4 Inverse Gyroid6.5 Conclusions; References; 7 Flexible and Stretchable Gyroid Metamaterials; 7.1 Introduction; 7.2 Stretchable Metamaterial; 7.3 Flexible Metamaterial; 7.4 Conclusions; References; 8 Metamaterial Sensors; 8.1 Introduction; 8.2 Capillary Condensation; 8.3 Solvent Vapour Sensing; 8.4 Conclusions; References; 9 Conclusions; [DELETE]; Appendix
Dimensions
unknown
Extent
1 online resource (x, 83 pages)
File format
unknown
Form of item
online
Isbn
9783319053325
Level of compression
unknown
Media category
computer
Media MARC source
rdamedia
Media type code
c
Note
SpringerLink
Other control number
10.1007/978-3-319-05332-5
Other physical details
illustrations (some color).
Quality assurance targets
not applicable
Reformatting quality
unknown
Sound
unknown sound
Specific material designation
remote
System control number
  • (OCoLC)884445007
  • (OCoLC)ocn884445007
Label
Optical metamaterials by block copolymer self-assembly, Stefano Salvatore
Link
https://ezproxy.lib.ou.edu/login?url=http://link.springer.com/10.1007/978-3-319-05332-5
Publication
Copyright
Note
"Doctoral thesis accepted by the University of Cambridge, UK."
Antecedent source
unknown
Bibliography note
Includes bibliographical references
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
  • Supervisor's Foreword; Abstract; Contents; 1 Introduction; 2 Background; 2.1 Block Copolymers; 2.1.1 Triblock Copolymer Morphologies; 2.1.2 Gyroid Morphology; 2.1.3 Block Copolymer Applications; 2.2 Metamaterials; 2.2.1 Chiral Metamaterial; 2.2.2 Surface Plasmons; 2.2.3 Gyroid Theoretical Models; References; 3 Gyroid Metamaterial Fabrication; 3.1 Introduction; 3.2 Substrate Preparation; 3.3 I-S-O Triblock Copolymer; 3.3.1 Thermal Annealing; 3.3.2 Drying-Annealing; 3.3.3 Solvent Vapour Annealing; 3.4 PFS-b-PLA Diblock Copolymer; 3.5 Metal Deposition; 3.6 Film Morphology Control
  • 3.7 ConclusionsReferences; 4 Gyroid Metamaterial Characterization; 4.1 Introduction; 4.2 Transmission Electron Microscopy; 4.3 Electric Characterization; 4.4 Optical Properties; 4.4.1 Single Gyroid; 4.4.2 Film Thickness Effects; 4.4.3 Disorder Effects; 4.4.4 Double and Silver Gyroids; 4.5 Conclusions; References; 5 Tuning Methods; 5.1 Introduction; 5.2 Unit Cell Control; 5.3 Filling Fraction Variation; 5.4 Surrounding Medium Effects; 5.5 Conclusions; References; 6 Hollow Gyroid; 6.1 Introduction; 6.2 Hollow Gyroid Fabrication; 6.2.1 Optical Properties; 6.3 Carbon Hollow Gyroid
  • 6.4 Inverse Gyroid6.5 Conclusions; References; 7 Flexible and Stretchable Gyroid Metamaterials; 7.1 Introduction; 7.2 Stretchable Metamaterial; 7.3 Flexible Metamaterial; 7.4 Conclusions; References; 8 Metamaterial Sensors; 8.1 Introduction; 8.2 Capillary Condensation; 8.3 Solvent Vapour Sensing; 8.4 Conclusions; References; 9 Conclusions; [DELETE]; Appendix
Dimensions
unknown
Extent
1 online resource (x, 83 pages)
File format
unknown
Form of item
online
Isbn
9783319053325
Level of compression
unknown
Media category
computer
Media MARC source
rdamedia
Media type code
c
Note
SpringerLink
Other control number
10.1007/978-3-319-05332-5
Other physical details
illustrations (some color).
Quality assurance targets
not applicable
Reformatting quality
unknown
Sound
unknown sound
Specific material designation
remote
System control number
  • (OCoLC)884445007
  • (OCoLC)ocn884445007

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