The Resource Metal free C-H functionalization of aromatics : nucleophilic displacement of hydrogen, edited by Valery Charushin, Oleg Chupakhin

Metal free C-H functionalization of aromatics : nucleophilic displacement of hydrogen, edited by Valery Charushin, Oleg Chupakhin

Label
Metal free C-H functionalization of aromatics : nucleophilic displacement of hydrogen
Title
Metal free C-H functionalization of aromatics
Title remainder
nucleophilic displacement of hydrogen
Statement of responsibility
edited by Valery Charushin, Oleg Chupakhin
Contributor
Editor
Subject
Genre
Language
eng
Summary
The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field
Member of
Cataloging source
GW5XE
Dewey number
547.604593
Illustrations
illustrations
Index
no index present
Language note
English
LC call number
QD331
Literary form
non fiction
Nature of contents
  • dictionaries
  • bibliography
http://library.link/vocab/relatedWorkOrContributorName
  • Charushin, Valery N.
  • Chupakhin, O. N.
Series statement
Topics in heterocyclic chemistry
Series volume
37
http://library.link/vocab/subjectName
  • Nucleophilic reactions
  • Aromatic compounds
  • Chemistry
  • Organic Chemistry
  • Industrial Chemistry/Chemical Engineering
  • Electrochemistry
Label
Metal free C-H functionalization of aromatics : nucleophilic displacement of hydrogen, edited by Valery Charushin, Oleg Chupakhin
Link
https://ezproxy.lib.ou.edu/login?url=http://link.springer.com/10.1007/978-3-319-07019-3
Instantiates
Publication
Antecedent source
unknown
Bibliography note
Includes bibliographical references
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
  • Intro; Preface; Reference; Contents; Metal-Free C-H Functionalization of Aromatic Compounds Through the Action of Nucleophilic Reagents; 1 Introduction; 2 Historical Aspects of the SNH Reactions; 3 The Key Features and Scope of the SNH Reactions; 3.1 Oxidative Version of the SNH Reactions; 3.2 Eliminative Version of the SNH Reactions; 4 Aromatic and Heteroaromatic Substrates; 4.1 Unactivated Arenes; 4.2 Arenes and Hetarenes Activated by the Nitro Group; 4.3 Arene-Metal Complexes; 4.4 Metallabenzenes; 4.5 Azines, Quaternary Azinium Salts, and Azine N-Oxides; 4.6 Azoles; 4.7 Macroheterocycles
  • 5 Nucleophilic Reagents5.1 Nitrogen-Centered Nucleophiles; 5.1.1 Ammonia, Primary, and Secondary Aliphatic Amines; 5.1.2 Aromatic Amines as N-Nucleophiles; 5.2 Oxygen-Centered Nucleophiles; 5.2.1 Water; 5.2.2 Alcohols; 5.3 Carbon-Centered Nucleophiles; 5.3.1 Carbanions Generated from C-H-Active Compounds; 5.3.2 Grignard Reagents; 5.3.3 Carbanions Generated from Ferrocenes and Cymantrenes; 5.3.4 Carbanions Generated from Carboranes; 5.3.5 Carbanions Generated from Nitronyl Nitroxide Radicals; 5.3.6 Aromatic Amines as C-Nucleophiles; 5.3.7 Phenols as C-Nucleophiles; 5.4 P-Nucleophiles
  • 5.5 S-Nucleophiles6 Intramolecular SNH Reactions; 7 Tandem SNH-SNH, SNH-SNX, and SNH-Metal-Catalyzed Cross-Coupling Reactions; 8 Electrochemical Version of the SNH Reactions; 9 Mechanistic Aspects of the SNH Reactions; 9.1 Electron Transfer Complexes Between Reactants; 9.2 Formation of Intermediate sigmaH-Adducts; 9.2.1 Spectroscopic Evidence for the Formation of sigmaH-Adducts; 9.2.2 X-Ray Data; 9.3 Oxidation of Intermediate sigmaH-Adducts; 10 Concluding Remarks; References; Nucleophilic Substitution of Hydrogen in Arenes and Heteroarenes; 1 Introduction
  • 2 Vicarious Nucleophilic Substitution of Hydrogen2.1 Mechanism; 2.2 Scope of the Reaction; 3 Oxidative Nucleophilic Substitution of Hydrogen; 4 Conversion of sigmaH Adducts into Nitrosoarenes; 5 Introduction of Substituents into Electron-Deficient Heterocycles via Nucleophilic Substitution of Hydrogen; 5.1 Carbon Substituents; 5.2 Hydroxylation; 5.3 Amination; 6 Construction of Heterocyclic Compounds via Nucleophilic Substitution of Hydrogen; 6.1 Indoles; 6.2 Quinolines; 6.3 2,1-Benzisoxazoles; 6.4 Phenazines and Other Heterocyclic Compounds from 2-Nitrosodiphenylamines
  • 6.5 Miscellaneous Syntheses of Heterocycles7 Conclusion; References; Direct Functionalization of C-H Fragments in Nitroarenes as a Synthetic Pathway to Condensed N-Heterocycles; 1 Introduction; 2 Synthesis of Condensed N-heterocycles via Nucleophilic Substitution of Hydrogen (SNH) in Nitroarenes; 2.1 Vicarious Nucleophilic Substitution of Hydrogen; 2.2 Oxidative Nucleophilic Substitution of Hydrogen; 3 Barton-Zard Reaction; 4 Mannich Cyclization of Anionic Adducts of Nitroarenes; 5 Pericyclic Reactions of Nitroarenes; 5.1 [4+2]-Cycloaddition Reactions; 5.2 [3+2]-Cycloaddition Reactions
Dimensions
unknown
Extent
1 online resource.
File format
unknown
Form of item
online
Governing access note
License restrictions may limit access
Isbn
9783319070186
Level of compression
unknown
Media category
computer
Media MARC source
rdamedia
Media type code
c
Note
SpringerLink
Other control number
10.1007/978-3-319-07019-3
Quality assurance targets
not applicable
Reformatting quality
unknown
Sound
unknown sound
Specific material designation
remote
System control number
  • (OCoLC)890642477
  • (OCoLC)ocn890642477
Label
Metal free C-H functionalization of aromatics : nucleophilic displacement of hydrogen, edited by Valery Charushin, Oleg Chupakhin
Link
https://ezproxy.lib.ou.edu/login?url=http://link.springer.com/10.1007/978-3-319-07019-3
Publication
Antecedent source
unknown
Bibliography note
Includes bibliographical references
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
  • Intro; Preface; Reference; Contents; Metal-Free C-H Functionalization of Aromatic Compounds Through the Action of Nucleophilic Reagents; 1 Introduction; 2 Historical Aspects of the SNH Reactions; 3 The Key Features and Scope of the SNH Reactions; 3.1 Oxidative Version of the SNH Reactions; 3.2 Eliminative Version of the SNH Reactions; 4 Aromatic and Heteroaromatic Substrates; 4.1 Unactivated Arenes; 4.2 Arenes and Hetarenes Activated by the Nitro Group; 4.3 Arene-Metal Complexes; 4.4 Metallabenzenes; 4.5 Azines, Quaternary Azinium Salts, and Azine N-Oxides; 4.6 Azoles; 4.7 Macroheterocycles
  • 5 Nucleophilic Reagents5.1 Nitrogen-Centered Nucleophiles; 5.1.1 Ammonia, Primary, and Secondary Aliphatic Amines; 5.1.2 Aromatic Amines as N-Nucleophiles; 5.2 Oxygen-Centered Nucleophiles; 5.2.1 Water; 5.2.2 Alcohols; 5.3 Carbon-Centered Nucleophiles; 5.3.1 Carbanions Generated from C-H-Active Compounds; 5.3.2 Grignard Reagents; 5.3.3 Carbanions Generated from Ferrocenes and Cymantrenes; 5.3.4 Carbanions Generated from Carboranes; 5.3.5 Carbanions Generated from Nitronyl Nitroxide Radicals; 5.3.6 Aromatic Amines as C-Nucleophiles; 5.3.7 Phenols as C-Nucleophiles; 5.4 P-Nucleophiles
  • 5.5 S-Nucleophiles6 Intramolecular SNH Reactions; 7 Tandem SNH-SNH, SNH-SNX, and SNH-Metal-Catalyzed Cross-Coupling Reactions; 8 Electrochemical Version of the SNH Reactions; 9 Mechanistic Aspects of the SNH Reactions; 9.1 Electron Transfer Complexes Between Reactants; 9.2 Formation of Intermediate sigmaH-Adducts; 9.2.1 Spectroscopic Evidence for the Formation of sigmaH-Adducts; 9.2.2 X-Ray Data; 9.3 Oxidation of Intermediate sigmaH-Adducts; 10 Concluding Remarks; References; Nucleophilic Substitution of Hydrogen in Arenes and Heteroarenes; 1 Introduction
  • 2 Vicarious Nucleophilic Substitution of Hydrogen2.1 Mechanism; 2.2 Scope of the Reaction; 3 Oxidative Nucleophilic Substitution of Hydrogen; 4 Conversion of sigmaH Adducts into Nitrosoarenes; 5 Introduction of Substituents into Electron-Deficient Heterocycles via Nucleophilic Substitution of Hydrogen; 5.1 Carbon Substituents; 5.2 Hydroxylation; 5.3 Amination; 6 Construction of Heterocyclic Compounds via Nucleophilic Substitution of Hydrogen; 6.1 Indoles; 6.2 Quinolines; 6.3 2,1-Benzisoxazoles; 6.4 Phenazines and Other Heterocyclic Compounds from 2-Nitrosodiphenylamines
  • 6.5 Miscellaneous Syntheses of Heterocycles7 Conclusion; References; Direct Functionalization of C-H Fragments in Nitroarenes as a Synthetic Pathway to Condensed N-Heterocycles; 1 Introduction; 2 Synthesis of Condensed N-heterocycles via Nucleophilic Substitution of Hydrogen (SNH) in Nitroarenes; 2.1 Vicarious Nucleophilic Substitution of Hydrogen; 2.2 Oxidative Nucleophilic Substitution of Hydrogen; 3 Barton-Zard Reaction; 4 Mannich Cyclization of Anionic Adducts of Nitroarenes; 5 Pericyclic Reactions of Nitroarenes; 5.1 [4+2]-Cycloaddition Reactions; 5.2 [3+2]-Cycloaddition Reactions
Dimensions
unknown
Extent
1 online resource.
File format
unknown
Form of item
online
Governing access note
License restrictions may limit access
Isbn
9783319070186
Level of compression
unknown
Media category
computer
Media MARC source
rdamedia
Media type code
c
Note
SpringerLink
Other control number
10.1007/978-3-319-07019-3
Quality assurance targets
not applicable
Reformatting quality
unknown
Sound
unknown sound
Specific material designation
remote
System control number
  • (OCoLC)890642477
  • (OCoLC)ocn890642477

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